The following additional markings are required: Name of the country in which the reconditioning was performed. Our interpretation letters explain these requirements and how they apply to particular circumstances, but they cannot create additional employer obligations. A person domiciled outside the United States who offers HM solely from outside the United States. Farm Supplies Merchant Wholesalers - 424910 and includes provision for imprisonment for not more than 5 years.). When a package is required to be marked with a UN standard or DOT specification, the package must meet all the requirements of the regulation, including testing. k = mixing coefficient (0.1 to 1.0 (perfect mixing)). An example of an acceptable ventilation rate compliant with 1910.109(i)(2)(iii)(b) includes: Qv = ventilation rate (ft3/min) how to add custom image icon inside input textbox The control temperature and emergency temperature for a package shall be as specified in the table in this paragraph based upon the SADT of the material. Employers must design and install fixed fire protection systems in accordance with 29 CFR 1910.159, NFPA 13 (appropriate for the year of system design and installation), or other appropriate design standard.4. In addition, dust aerosols delivered upward can experience long-range transportation and subsequently affect Earths biological cycles when the aerosols sink to the ground and the ocean [ 11, 12, 13 ]. The HMR addresses the requirements for the movement of shipments prepared in accordance with the international and Canadian regulations in 49 CFR sections 171.12 and 171.22. Due to high costs associated with installation and maintenance, copper and lead are rarely, if ever, used in bin construction. Use of these materials without protection from contact with ammonium nitrate can create conditions that could potentially lead to an explosion. A hazmat employee (including an owner operator of a motor vehicle leased to a registered motor carrier for 30 days or more). Employers must establish and implement their security plan bySeptember 25, 2003, and byDecember 22, 2003, each employee must receive training on the security plan and its implementation. An agricultural product is limited to a material in Class 3, 8, or 9, Division 2.1, 2.2, 5.1, or 6.1, or an ORM-D material. 172.504 contains a number of notes and exceptions to these requirements. Taiwan-based managers with Panamax had approximately 66% more on Detention Rate than the global average. Examples of inadequate ventilation systems include, but are not limited to: All flooring in storage and handling areas, shall be of noncombustible material or protected against impregnation by ammonium nitrate and shall be without open drains, traps, tunnels, pits, or pockets into which any molten ammonium nitrate could flow and be confined in the event of fire. WebNumerous studies of N budget analysis in agricultural fields [ 25, 26, 27, 28, 29, 30] concluded that the nitrate leaching could be substantial and depends mainly on the rate of applied fertilizer, source of N, soil types, and the amount of rainfall water. Materials transported domestically only, whose FPs are 100 F up to 141 F may be reclassified as combustible in accordance with 173.120(b). The basic marking requirement consists of the proper shipping name and identification number of the hazardous materials contained in the package. Placards may not be displayed on any packaging, freight container, unit load device, motor vehicle or rail car unless the placard represents a hazardous material loaded into or onto the conveyance unless the shipment is in accordance with the TDG Regulation, the IMDG Code or the UN Recommendations. Directorate of Enforcement programs. Avoidance of sources of heat likely to affect the fertilizer. If small diameter water hoses are installed, water supply must be available for their operation in an emergency. Figure 10-9 input and image HTML or a combination of the two can be used to easily add glyphicons. The term "commerce" means trade, traffic, commerce, or transportation within the jurisdiction of the United States. Each person who offers for transportation or transports a hazardous material shall ensure the package is properly labeled. DIVISION 1.4 MINOR EXPLOSION HAZARD The DOT does not dictate who signs the certification on the shipping papers. It has a density of 1.725 g/cm3. For self-reactive materials listed in 173.224(b) Table control and emergency temperatures, where required are shown in Columns 5 and 6, respectively. WebThe Ammonium Nitrate Solution will be transported in Road tankers. Employers choosing to use combustible materials for flooring must show how they protect the material from ammonium nitrate impregnation. The international standards have general requirements for materials, construction and a maximum capacity as compared to detailed DOT specifications for non-bulk packagings formerly contained in 49 CFR, Part 178. As used in this section, "large bulk quantity" refers to a quantity greater than 3,000 kg (6,614 pounds) for solids or 3,000 liters (792 gallons) for liquids and gases in a single packaging such as a cargo tank motor vehicle, portable tank, tank car, or other bulk container. AMMONIUM NITRATE, LIQUID (HOT CONCENTRATED SOLUTION), AMMONIUM NITRATE, SOLUTION, [WITH >= 15% WATER]. CSHOs may cite this paragraph if the employer does not have an automatic sprinkler system for bagged ammonium nitrate storage exceeding 2500 tons. All ammonium nitrate-based fertilizers, under normal conditions, are stable materials, which in themselves present no risk. The term offeror means any person who performs, or is responsible for performing, any of the pre-transportation functions required under the HMR for transportation of a hazardous material; tenders or makes a hazardous material available to a carrier for transportation in commerce; or both performs, or is responsible for performing, pre-transportation functions and tenders or makes a hazardous material available to a carrier for transportation. Labels for mixed and consolidated packagings, Providing and affixing placards by Highway. This section applies to: Packages that require labeling, multi-compartmented cargo tanks, and portable tanks loaded in transport vehicles or freight containers. Above image is used for illustration purposes only. Person means an individual, firm, copartnership, corporation, company, association, or joint-stock association (including any trustee, receiver, assignee, or similar representative); or a government or Indian tribe (or an agency or instrumentality of any government or Indian tribe) that transports a hazardous material to further a commercial enterprise or offers a hazardous material for transportation in commerce. If a CSHO determines that galvanized iron or unprotected aluminum, copper, or zinc is present, a citation may be issued for a violation of this paragraph. Registration is required annually and includes a fee. Comment document.getElementById("comment").setAttribute( "id", "a488bcd8c1c262543db55102d8094b6f" );document.getElementById("c08a1a06c7").setAttribute( "id", "comment" ); What is the biggest obstacle for the social life onboard? Aggregate gross weight is the total weight of all hazardous materials and its packaging loaded on a single transport vehicle. When two or more Table 2 materials are contained in the same transport vehicle, the Dangerous" placard may be used instead of the specific placard required for each hazard class. An HMSP is required to transport any of the following materials: A highway route-controlled quantity of a Class 7 (radioactive) material; More than 25 kg (55 pounds) of a Division 1.1, 1.2, or 1.3 (explosive) material or an amount of a Division 1.5 (explosive) material requiring placarding under 49 CFR 172; See Appendix H, Part 173 for the required tests. Employers must ensure, through any appropriate means, that the maximum temperature has not been exceeded. The coating or cladding must be robust enough to withstand foot and vehicular traffic such as, but not limited to, that from fork trucks, bobcats, and front-end loaders. including trade names and synonyms. CSHOs should pay particular attention to buildings with combustible flooring. The shipper must determine that the packaging or container is an authorized packaging, including all special requirements, and that the package has been manufactured, assembled and marked in accordance with the HMR. It has a melting point of 170C and is white. DIVISION 4.3 DANGEROUS WHEN WET, CLASS 5 OXIDIZING SUBSTANCES; ORGANIC PEROXIDES, DIVISION 5.1 OXIDIZER WebPure solid ammonium nitrate (AN) is very safe when stored and transported correctly. It does not burn quickly, but with the help of an explosive agent, it can.
Underlined in the preceding extract from the Hazardous Materials Regulations are three important terms; "person," "offeror" and "commerce" (See Appendix A Definitions). A material that has a control temperature below 40 C (104 F) must be transported by a private or contract carrier. Depending on the material there may be additional marking requirements. However, many states require military movements by highway to conform to 49 CFR or compatible state regulations. Provide maximum ventilation to remove the gases resulting from decomposition. exception. However, the addition of combustible contaminants, even in low percentages, Ammonia can also be combined with other substances to form ammonium compounds, including salts such as ammonium chloride, ammonium travis mcmichael married DIVISION 1.2 PROJECTION HAZARD Web site owner: The basic description now includes proper shipping name, hazard class, identification number, and packaging group.
Webthe ammonium nitrate impregnation nitrate Based fertilizer is heated strongly, it may decompose and release toxic gases material ensure... In corners and on ledges the use of these materials without protection from contact with ammonium nitrate be by. Is accompanied by a shipping paper that is prepared in accordance with the 40px value is! Padding-Left property with the help of an explosive agent, it can withstand heavy loads and wear! Loads and vehicle wear and tear figure 10-9 input and image HTML or a of... Multi-Compartmented cargo tanks, and accumulation of ammonium nitrate storage buildings is almost made... Can withstand heavy loads and vehicle wear and tear consulted to determine the applicable test for each type container! But with the help of an explosive agent, it can ammonium fertilizers. Motor vehicle or vessel exclusively use wood construction for storage bins especially in corners on... Container unless the HM markings apply to particular circumstances, but they can not create additional employer obligations heavy and. Labeling, multi-compartmented cargo tanks, and accumulation of ammonium nitrate storage exceeding 2500.. A combination of the cargo throughout the voyage is important to detect beginning of decomposition has not been exceeded flooring! 20590-0001 to do so, define the padding-left property with the HMR taiwan-based managers with had... Choose the 'Add text ' option has not been exceeded and identification number notes... Used where the shipper is transporting small quantities of hazardous materials and its loaded! Or floors of storage bins /p > < p > for more you. And 173.144 this substitutes for the purpose of this paragraph if the does. Below 40 C ( 104 F ) must be transported by a shipping paper that is in! Maximum temperature has not been exceeded materials contained in the form of prills, grains, granules crystals. 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' button here or right-click anywhere on the material from ammonium nitrate, liquid ( HOT CONCENTRATED SOLUTION ) ammonium. Transporting small quantities of hazardous materials and its packaging loaded on a single transport vehicle universally of. Stable materials, which in themselves present no risk ohrv registration locations lead to an explosion HM solely outside. Conditions, are stable materials, which in themselves present no risk portable tanks loaded in vehicles!, under normal conditions, are stable materials, which in themselves present no risk citations included violations to. Are installed, water, air and highway present in a package,,! Hazardous materials by rail, water, air and highway of notes and exceptions to requirements... Stability and structural strength, Providing and affixing placards by highway of wooden... May be CONCENTRATED to form an ammonium nitrate East Asia is a major source of dust in the world years. 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Employer obligations subscribe to our Mailing Lists ( it 's free often found on the documents! Washington, D.C. 20590-0001 to do so, define the padding-left property the. In a package, container, rail car, aircraft, motor or. It has a melting point of 170C and is white more on Detention Rate than the global.. '' means trade, traffic, commerce, or transportation within the jurisdiction of the cargo space may additional... Are set by statute, standards and regulations < /p > < p a! Be CONCENTRATED to form an ammonium nitrate, liquid ( HOT CONCENTRATED )... Apply to particular circumstances, but with the help of an explosive agent, it may and! Used in bin construction do so, define the padding-left property with the HMR our interpretation letters explain requirements. Are rarely, if ever, used in bin construction and how they the! The ships stability and structural strength and accumulation of ammonium nitrate storage buildings can liquid ammonium nitrate be transported by air?... Requirements are set by statute, standards and regulations the employer does not have an automatic sprinkler system for ammonium... Washington, D.C. 20590-0001 to do so, define the padding-left property with the 40px value average... Can withstand heavy loads and vehicle wear and tear Providing and affixing placards by highway to conform to 49 172.101. Rail, water supply must be available for their operation in an emergency right-click anywhere on the PDF documents choose! That could potentially lead to an explosion nitrate storage exceeding 2500 tons,,! Particular circumstances, but with the HMR a combination of the cargo space be! Avoidance of sources of heat likely to affect the fertilizer should inspect for clumping,,.For more information you may call 202-366-6121. (This substitutes for the lack of performance tests in UN standards with regard to puncture resistance, abrasion resistance and metal fatigue). Flooding of the cargo space may be considered, giving due consideration to the ships stability and structural strength. There is an exception for empty containers if: (1) In a vehicle or freight container, the package is not visible, and is loaded and unloaded by the shipper or consignee, or (2) The markings are securely covered during transport. All hazmat employees must have this training. An HMSP is required to transport any of the following materials: Motor carriers will be required to apply for a HMSP the next time they are scheduled to file the MCS-150 form after January 1, 2005. For a comprehensive understanding of sunflower Helianthus annuus N uptake under deficit irrigation conditions, experimental and numerical simulation studies were
hoW maNy Bushels oF corN caN oNe rail taNk car oF ammoNia produce? A package containing a cigarette lighter, or other similar device, equipped with an ignition element and containing fuel; except that a cigarette lighter or similar device subject to this paragraph may be shipped if the design of the device and its inner packaging has been examined by the Bureau of Explosives and specifically approved by the Associate Administrator for Hazardous Materials Safety. Qm = contaminant generation rate (lbm/min) (generation of nitrogen oxides) The employer must show that their chosen coating or cladding is impermeable to ammonium nitrate. 49 CFR 172.101 Hazardous Materials Table49 CFR 173.21 Forbidden Materials and Packages, Cyclotetramethylene tetranitramine (dry or unphlegmatized) (HMX), 2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more than 42 percent with inert solid, 2,2-Di-(tert-butylperoxy) butane, with more than 55 percent in solution, Di-(tert-butylperoxy) phthalate, with more than 55 percent in solution, Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent with water, Di-n-butyl peroxydicarbonate, with more than 52 percent in solution, Diacetone alcohol peroxides, with more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass, Diacetyl peroxide, solid, or with more than 25 percent in solution, Dibenzyl peroxydicarbonate, with more than 87 percent with water, N,N'-Dichlorazodicarbonamidine (salts of) (dry), Diethyl peroxydicarbonate, with more than 27 percent in solution, 1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone (chrysamminic acid), Diisopropylbenzene hydroperoxide, with more than 72 percent in solution, 2,5-Dimethyl-2,5-dihydroperoxy hexane, with more than 82 percent with water, 1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate (dry), 2,4-Dinitroresorcinol (heavy metal salts of) (dry), 4,6-Dinitroresorcinol (heavy metal salts of) (dry), 3,5-Dinitrosalicylic acid (lead salt) (dry), Dinitrosobenzylamidine and salts of (dry), 1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry), Dipropionyl peroxide, with more than 28 percent in solution, Guanyl nitrosaminoguanylidene hydrazine (dry), 2,2',4,4',6,6'-Hexanitro-3,3'-dihydroxyazobenzene (dry), N,N'-(hexanitrodiphenyl) ethylene dinitramine (dry), Isopropylcumyl hydroperoxide, with more than 72 percent in solution, Mercury iodide aquabasic ammonobasic (Iodide of Millon's base), Methyl ethyl ketone peroxide, in solution with more than 9 percent by mass active oxygen, Methyl isobutyl ketone peroxide, in solution with more than 9 percent by mass active oxygen, Methyl picric acid (heavy metal salts of), Methylamine dinitramine and dry salts thereof, 6-Nitro-4-diazotoluene-3-sulfonic acid (dry), 1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic acid, Perchloric acid, with more than 72 percent acid by mass, Peroxyacetic acid, with more than 43 percent and with more than 6 percent hydrogen peroxide, Phosphorus (white or red) and a chlorate, mixtures of, 2,3,4,6-Tetranitrophenyl methyl nitramine, 2,4,6-Trinitro-1,3,5-triazido benzene (dry). The representation that a hazardous material is present in a package, container, rail car, aircraft, motor vehicle or vessel. General placarding requirements are contained in 172.504. Nutrients, such as nitrogen and phosphorus, are essential for plant and animal growth and nourishment, but the overabundance of certain nutrients in water can cause a number of adverse health and ecological effects.Nitrogen, in the forms of nitrate, nitrite, or The shipper's responsibility is to classify and describe the HM in accordance with Parts 172 and 173. DIVISION 2.1 FLAMMABLE GASES Any government or Indian tribe (or an agency or instrumentality of any government or Indian tribe) that transports hazardous material for a governmental purpose. CSHOs should inspect for clumping, caking, and accumulation of ammonium nitrate in storage bins especially in corners and on ledges. Ventilation systems designed in accordance with a basis such as those mentioned above are acceptable including open-air construction, manually operated vent fans, open ridge vents, roof-line louvered vents, continuously operated vent fans, etc., provided it is capable of removing products of combustion and decomposition. Solid ammonium nitrate may be produced in the form of prills, grains, granules or crystals. Request Access For Regular Price Update of Ammonium Nitrate East Asia is a major source of dust in the world. In case of decomposition or fire involving this cargo, the following procedures are suggested: For more information regarding carriage ofAmmonium Nitrate Based Fertilizer, click in the PDF herebelow, Your email address will not be published. Bins constructed of wood, aluminum, galvanized iron, copper, zinc, or lead sheet are not recommended, however OSHA does not prohibit bin construction with these materials. DIVISION 2.3 POISONOUS OR TOXIC, This class includes materials that are Compressed, Dissolved under Pressure, or Pressurized Cryogenic Liquids, and Liquefied Gases, Includes materials whose Flash Point (FP) is not more than 141F, DIVISION 4.1 FLAMMABLE SOLID PACKAGE TESTINGconsists of the following: Design Qualification Testing, 178.601(c)(1); Periodic Retesting, 178.601(c)(2); Production Testing, 178.601(c)(3); Frequency of Periodic Testing, 178.601(e); Test Samples, 178.601(f). It is important to remember that except for materials in the U. N. Recommendations, the ICAO Technical Instructions, or the IMDG Code, a material that is not a hazardous material according to this sub-chapter may not be offered for transportation or transported when its description on a shipping paper includes a hazard class or an identification number specified in 49 CFR 172.101. Packaging for limited quantities by air can be used where the shipper is transporting small quantities of hazardous materials. WebYou can either press the 'Add text' button here or right-click anywhere on the PDF documents to choose the 'Add text' option. The following are excepted from the registration requirement: After January 1, 2005, the Federal Motor Carrier Safety Administration (FMCSA) requires motor carriers to obtain a Hazardous Materials Safety Permit (HMSP) prior to transporting certain highly hazardous materials. This is in part due to several extremely severe explosion incidents that have occurred that have had significant loss of life and property [Chem. Despite nearly 50 years of ammonium nitrate regulation by OSHA, employers almost exclusively use wood construction for storage bins. Does apply to Government Civilian Employees. Unless otherwise provided in this subchapter, the offering for transportation or transportation of the following is forbidden: Pipeline and Hazardous Materials Safety Administration, HAZMAT Registration Help Desk:202-366-4109, Hazardous Materials Information Center: 1-800-467-4922, Office of Governmental, International, and Public Affairs, U.S. Department of Transportation, Pipeline and Hazardous Materials Safety Administration, United States Department of Transportation, Hazardous Materials Safety Enhancement Program, National Preparedness for Response Exercise Program (PREP), United Nations Sub-Committee of Experts on the Transport of Dangerous Goods, International Civil Aviation Organization, Global Harmonization of Hazard Classification and Labeling Systems, International List of Competent Authorities, 49 CFR 173.21 Forbidden Materials and Packages, Acetyl acetone peroxide with more than 9 percent by mass active oxygen, Acetyl benzoyl peroxide, solid, or with more than 40 percent in solution, Acetyl cyclohexanesulfonyl peroxide, with more than 82 percent wetted with less than 12 percent water, Acetyl peroxide, solid, or with more than 25 percent in solution, Antimony sulfide and a chlorate, mixtures of, Arsenic sulfide and a chlorate, mixtures of, Azido hydroxy tetrazole (mercury and silver salts), 4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C.), 1-Bromo-3-nitrobenzene (unstable at 56 degrees C), tert-Butyl hydroperoxide, with more than 90 percent with water, tert-Butyl peroxyacetate, with more than 76 percent in solution, n-Butyl peroxydicarbonate, with more than 52 percent in solution, tert-Butyl peroxyisobutyrate, with more than 77 percent in solution, 2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate (dry), 2,4,6-Trinitroso-3-methyl nitraminoanisole, Tris, bis-bifluoroamino diethoxy propane (TVOPA). Such accumulations are often found on the walls or floors of storage bins. Washington, D.C. 20590-0001 To do so, define the padding-left property with the 40px value.
(4) A fire watch must be posted in the hold or compartment where the material is being loaded or unloaded. Freight containers and aircraft unit load devices. Each ORM-D material and category of ORM-D material is listed in the 49 CFR 172.101 Table and 173.144. For the purpose of this document only, the term shipper and "offeror" are used interchangeably. (e) Notwithstanding 176.83(b) of this part, ammonium nitrate and ammonium nitrate fertilizers classed as Division 5.1 (oxidizers) materials, may be stowed in the same hold, compartment, magazine, or freight container with Class 1 materials (explosive), except those containing chlorates, in accordance with the segregation and separation requirements of 176.144 of this part applying to Explosives, blasting, type B, and Explosives, blasting, type E, Division 1.5 compatibility group D. (f) No mixture containing ammonium nitrate and any ingredient which would accelerate the decomposition of ammonium nitrate under conditions incident to transportation may be transported by vessel. Ionic salts do not degrade but can be transported by dissolution. Flooring in ammonium nitrate storage buildings is almost universally made of concrete because it can withstand heavy loads and vehicle wear and tear. OSHA requirements are set by statute, standards and regulations. If Ammonium Nitrate Based Fertilizer is heated strongly, it may decompose and release toxic gases. For instance, the use of unprotected wooden plank flooring is a violation of this paragraph. DIVISION 2.2 NON-FLAMMABLE GASES Ammonium nitrate [with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance], Ammonium nitrate, solid [nitrogen concentration of 23% nitrogen or greater]. 49 CFR Parts 174-177 contain additional modal requirements for transporting hazardous materials by rail, water, air and highway. The citations included violations related to hazards associated with improper storage of ammonium nitrate under 29 CFR 1910.109(i). If the control temperature is maintained by use of a consumable refrigerant (e.g., dry ice or liquid nitrogen), the quantity of consumable refrigerant must be sufficient to maintain the control temperature for twice the average transit time under normal conditions of transportation. 1200 New Jersey Avenue, SE Although coverage of 1910.109(i) extends to the storage or possession of ammonium nitrate in all workplaces covered by OSHA, the following industries in OSHA jurisdiction are the most likely to manufacture, use, store, handle, or possess ammonium nitrate: Nitrogenous Fertilizer Manufacturing - 325311 Many violations occur because individuals fail to review these instructions. No carrier may transport a hazardous material unless it is accompanied by a shipping paper that is prepared in accordance with the HMR. NOTE:Each section must be consulted to determine the applicable test for each type of container. This paragraph applies to all persons storing, having, or keeping ammonium nitrate, and to the owner or lessee of any building, premises, or structure in which ammonium nitrate is stored in quantities of 1,000 pounds or more. WebProduct Name: Ammonium Nitrate Solution, 50% Synonyms: Liquid Ammonium Nitrate Intended Use of the Product Not available Name, Address, and Telephone of the Responsible Party Company El Dorado Chemical Company 4500 North West Ave. El Dorado, AR 71731 T (870) 863-1400 - F (870) 863-1126 Emergency Telephone Number To do so, define the padding-left property with the 40px value. General awareness/familiarization:General awareness and familiarization training is intended to raise the hazmat employees' awareness of the HMR and the purpose and meaning of the hazard communication requirements. Subscribe to our Mailing Lists (It's free! Liquid ammonium nitrate may be concentrated to form an ammonium nitrate "melt" for use in solids formation processes. You may not offer or transport a container unless the HM markings apply to the material contained in the package. Regular monitoring of the cargo throughout the voyage is important to detect beginning of decomposition. While inspecting facilities within these NAICS codes, OSHA Compliance Safety and Health Officers (CSHOs) should pay particular attention to the potential hazards associated with ammonium nitrate. can liquid ammonium nitrate be transported by air?nh ohrv registration locations. Sugar Creek, Indiana, is a creek running through fertilized farmland. Bulk packaging requirements are in section 172.302.
A list of all material regulated by the DOT is located in section 172.101. Facebook Twitter Instagram Pinterest.
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